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81.
This study describes the development of multilayer metal-dielectric graded index solar selective coatings in which the metallic volume fraction increases with depth, from top (air–film interface) to bottom (film–substrate interface). The work is based on computer simulation followed by validation through fabrication of the coatings and optical measurements. The influence of the choice of the number of layers present in a graded index composite selective absorber and results obtained for a new destructive interference bilayer (four-layer system) coating, designed using the computer model, were studied. The design and optimization of the composite coating was undertaken using a computer tool developed within this program of research employing Bruggeman and Maxwell–Garnett effective medium formalisms. The design tool enabled all key design parameters, with the exception of particle size and orientation, to be varied systematically to permit the sensitivity of the optical properties of the selective absorber coating to be studied.The model was validated with a supporting program of experimental research in which many different selective absorbers were prepared by co-sputtering of metal and dielectric materials.Although the best compositional gradation can be achieved by increasing the number of layers, the variation in optical performance beyond a certain number of layers is minimal. The destructive interference produced between adjacent layers contributes to the absorptance. The effect of the number of layers (single, four and 10) has been calculated for various materials such as nickel, vanadium, tungsten, cobalt and chromium based coatings. Solar absorptance of 0.98 and 0.96 was achieved by simulation and experimental findings with less than 0.07 thermal emittance at 300 K for 200 nm thick, 4-PGSAC (four-layer system) of V : Al2O3 composites. Other designs showed lower optical performance for all the material combinations regardless of their individual optical properties. Use of such thin film coating on the absorbers of solar thermal appliances can reduce thermal losses significantly, which could be of importance to the relevant industry. 相似文献
82.
The combination of favorable features of tensile mode dynamic mechanical analysis and torsional braid analysis leads to a useful method for cure monitoring of thermoset coatings. This sensitive technique allows the observation of cure reactions over a wide time and temperature range, thus including gelation and long-term curing in one measurement. Isothermal baking can be simulated realistically, since evaporation of volatile compounds like solvents or blocking agents is not hindered and the sample film is in direct contact with the heating atmosphere. Examples are given showing the cure behavior of automotive clear coats and electro coats depending on parameters like crosslinker type and catalytic agents. 相似文献
83.
84.
探讨了新型保健绿豆纤维功能饮料的生产工艺,对影响产品品质的几个主要因素进行了较为深入的探讨,提出了生产绿豆纤维功能饮料的最佳工艺条件。 相似文献
85.
在分析负离子净化空气的原理及环境状况与空气中负离子浓度的关系基础上,应用负离子功能粘胶长丝和涤纶短纤混纺纱针织物作为空调滤材,利用空调出风(冷风)使针织物滤材试样飘动,相互拍击摩擦,使空调出风中的氧气分子和水分发生有效电离,从而产生大量空气负离子。实验结果表明,负离子功能粘胶长丝和涤纶短纤混纺纱针织物都有释放空气负离子的功能;而且在同规格纱线的平针组织、双罗纹组织、蜂巢组织和畦编组织针织物中,畦编组织针织物释放的负离子量最大;空气相对湿度对功能材料释放负离子数量有明显影响,当相对湿度在65%~70%时释放的负离子量趋于最大。 相似文献
86.
87.
The determination of the Young’s modulus and damping coefficient Q−1 by means of non-destructive vibrating techniques has been applied to bulk and coated industrial materials. Extensions of a previous analytic model of composite beam allow to determine accurately the macroscopic modulus of each component of multilayered structural materials as coated superalloys or nitride-hardened steels. Furthermore, the study of glasses and polymers has been investigated. An attempt of normalisation of the modulus versus temperature curves allows to establish master curves depending on the specific structure, from metallic glasses to polymeric glasses. Finally a comparison of dynamical modulus and Q−1 values measured between resonant (>1 kHz) and subresonant techniques (10−3 to 10 Hz) in relation to the loading frequencies applied in real conditions has been under folder. For metallic materials such as forged or rolled titanium alloys, the brittle-to-fragile transition occurs abruptly or smoothly with a shift of 300 K following the range of excitation frequencies. 相似文献
88.
H. -C. Chiao H. -L. Lin X. -T. Li C. -X. Ding 《Journal of Thermal Spray Technology》1992,1(2):111-115
Diamond growth with rates up to 100 to 140 μm/hr was achieved using an oxygen-acetylene combustion spraying technique in an
atmospheric environment. Investigations on the processing indicated that the gas flow ratio, substrate position, substrate
temperature, temperature distribution, and substrate pretreatment were the most important factors affecting the growth of
diamond crystals. Evaluation by means of X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and electron
probe microanalysis showed that the synthesized diamond was nearly perfect in morphology, structure, and purity. 相似文献
89.
Gradient-corrected density functional theory was used to investigate the adsorption of H2S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H2S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H2S decomposition giving rise to adsorbed S and H were determined. Both H2S(ad) → SH(ad) + H(ad) and SH(ad) → S(ad) + H(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H2S on Pd(1 1 1) surface is a facile process. 相似文献
90.
William Kent 《Computer Standards & Interfaces》1991,13(1-3):201-206
OSQL is the object-oriented database language developed for the Iris object-oriented database management system at Hewlett-Packard Laboratories. Its three fundamental constructs are objects, types, and functions. This paper provides an overview of the underlying concepts and some important features of OSQL. 相似文献